doi:

DOI: 10.3724/SP.J.1123.2017.06025

Chinese Journal of Chromatography (色谱) 2017/35:10 PP.1073-1079

Simultaneous determination of nine perfluorinated compound precursors in atmospheric precipitation by solid phase extraction and ultra performance liquid chromatography with tandem mass spectrometry


Abstract:
A high-throughput detection method has been developed for the determination of nine perfluorinated compound precursors (PFCPs) in atmospheric precipitation by solid phase extraction-ultra performance liquid chromatography coupled with electrospray ionization tandem mass spectrometry (SPE-UPLC-ESI-MS/MS). The atmospheric precipitation samples were concentrated and purified with HLB solid phase extraction cartridges. The UPLC separation was performed on an HSS T3 column (100 mm×2.1 mm, 1.7 μm) utilizing a gradient elution program of methanol and water as the mobile phases at a flow rate of 0.2 mL/min. The MS/MS detection was performed under negative electrospray ionization (ESI-) in multiple reaction monitoring (MRM) mode. Good linearity was observed in the range of 0.05-5.00 μg/L, 0.50-50.0 μg/L or 5.00-500 μg/L with correlation coefficients from 0.9921 to 0.9995. The limits of detection (LODs) for the nine perfluorinated compound precursors were in the ranges of 0.05-7.9 ng/L. The recoveries ranged from 76.0% to 106% with the relative standard deviations between 0.72% and 13.7%. This method is characterized by high sensitivity and precision, extensive analytical range and quick analytical rate, and can be applied for the analysis of perfluorinated compound precursors in atmospheric precipitation.

Key words:solid phase extraction (SPE),ultra performance liquid chromatography-electrospray ionization-tandem mass spectrometry (UPLC-ESI MS/MS),perfluorinated compound precursors,atmospheric precipitation

ReleaseDate:2017-11-03 11:22:11



[1] Paul A G, Jones K C, Sweetman A J. Environ Sci Technol, 2009, 43(2):386

[2] Ahrens L, Shoeib M, Harner T, et al. Environ Sci Technol, 2011, 45(19):8098

[3] Lau C, Anitole K, Hodes C, et al. Toxicol Sci, 2007, 99:366

[4] Giesy J P, Naile J E, Khim J S, et al. Rev Environ Contam Toxicol, 2010, 202:1

[5] Eschauzier C, Beerendonk E, Scholte-Veenendaal P, et al. Environ Sci Technol, 2012, 46(3):1708

[6] United Nations Environment Programme. SC-4/17:Listing of Perfluorooctane Sulfonic Acid, Its Salts and Perfluorooctane Sulfonyl Fluoride. Fourth Meeting of the Conference of the Parties to the Stockholm Convention on Persistent Organic Pollutants, Geneva, 2009:1

[7] International Agency for Research on Cancer (IARC). Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man.[2016-12-22]. http://monographs.iarc.fr/ENG/Classification/latest_classif.php

[8] Peng S Y, Yan L J, Zhang J, et al. Chinese Journal of Chromatography, 2012, 30(2):123 彭思远, 严丽娟, 张洁, 等. 色谱, 2012, 30(2):123

[9] Zhang J H, Zhu Y J, Chen L G, et al. Asian Journal of Ecotoxicology, 2016, 11(2):658 张俊桦, 祝玉杰, 陈来国, 等. 生态毒理学报, 2016, 11(2):658

[10] Zhang M, Tang F L, Yu Y Y, et al. Environmental Science, 2015, 36(12):4471 张明, 唐访良, 俞雅雲, 等. 环境科学, 2015, 36(12):4471

[11] Li F S, Ni H, Huang H Y, et al. Environmental Science, 2017, 38(1):327 李法松, 倪卉, 黄涵宇, 等. 环境科学, 2017, 38(1):327

[12] Wang Y, Zhang P Y. Progress in Chemistry, 2010, 22(1):210 王媛, 张彭义. 化学进展, 2010, 22(1):210

[13] Shoeib M, Harner T, Vlahos P. Environ Sci Technol, 2006, 40(24):7577

[14] Wang J M, Pan Y Y, Shi Y L, et al. Scientia Sinica Chimica, 2011, 41(5):900 王杰明, 潘媛媛, 史亚利, 等. 中国科学:化学, 2011, 41(5):900

[15] Kim S K, Kannan K. Environ Sci Technol, 2007, 41(24):8328

[16] Liu W, Jin Y H, Quan X, et al. Environ Int, 2009, 35(4):737

[17] Liu W, Dong G H, Jin Y H, et al. Chinese Science Bulletin, 2009, 54(14):2440

[18] Zhang M, Tang F L, Yu Y Y, et al. Environmental Science, 2017, 38(8):3185 张明, 唐访良, 俞雅雲, 等. 环境科学, 2017, 38(8):3185

[19] Martin J W, Muir D C G, Moody C A, et al. Anal Chem, 2002, 74(3):584

[20] Shi Y, Yang L, Li J G, et al. Chinese Journal of Preventive Medicine, 2014, 48(7):628 石瑀, 杨琳, 李敬光, 等. 中华预防医学杂志, 2014, 48(7):628

[21] Zhang M, Tang F L, Yu Y Y, et al. Chinese Journal of Chromatography, 2014, 32(5):472 张明, 唐访良, 俞雅雲, 等. 色谱, 2014, 32(5):472

[22] Wang C, Lü Y B, Chen H J, et al. Chinese Journal of Chromatography, 2014, 32(9):919 王超, 吕怡兵, 陈海君, 等. 色谱, 2014, 32(9):919

[23] Taniyasu S, Kannan K, So M K, et al. J Chromatogr A, 2005, 1093(1/2):89

[24] Szostek B, Prickett K B, Malees A, et al. Rapid Commun Mass Sp, 2006, 20(19):2837

[25] Chang Y C, Chen W L, Bai F Y, et al. Anal Bioanal Chem, 2012, 402(3):1315

[26] Arvaniti O S, Asimakopoulos A G, Dasenaki M E, et al. Anal Methods, 2014, 6(5):1341

[27] Yu Y B, Tan P G, Liu Z X, et al. Chinese Journal of Analytical Chemistry, 2013, 41(8):1259 于彦彬, 谭丕功, 刘宗兴, 等. 分析化学, 2013, 41(8):1259

[28] Zhao Y Z, Xie Z W, Pan L D, et al. Chinese Journal of Chromatography, 2016, 34(3):289 赵云芝, 谢振伟, 潘乐丹, 等. 色谱, 2016, 34(3):289

[29] HJ 168-2010