DOI: 10.3724/SP.J.1077.2008.01067

Journal of Inorganic Materials (无机材料学报) 2008/23:5 PP.1067-1069

Chemical Reduction Synthesis of Hexagonal B-C-N Compound

Hexagonal B-C-N compounds were successfully synthesized by using hydrogen-free 1,3,5-trichlorotriazine and boron tribromide as reactants and metal sodium as reluctant through a chemical reduction synthesis method at 450℃. The synthesized sample was characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), selected area electron diffraction (SAED), electron energy loss spectroscope (EELS) and Fourier transformation infrared spectroscope (FTIR), respectively. The results indicate that the synthesized B-C-N compound is polycrystalline with hexagonal structure and its composition is B0.5C0.07N0.43.

Key words:hexagonal B-C-N compound,chemical reduction synthesis method,X-ray diffraction,electron energy loss spectroscopy

ReleaseDate:2014-07-21 14:21:04